You can create a new XML schema standard in the schema library in order to load the correct schema to validate XML documents containing a specific namespace.
Open an example XML document.
Select Tools->Schema Used to Validate XML.
Click 'Add Standard'.
Select the schema to be used when the namespace.
Ensure 'Use this entry when the namespace below are declared' is checked.
Now whenever you open an XML document that contains the namespace, the correct schema will be used.
See also the product help:
Associating a schema with an XML Document
Related Knowledge Base Articles:
How to validate an existing XML Document against an XML Schema
How to stop the schema library from loading schema for my xml document
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